The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules. 相似文献
We analyzed the spatial local accuracy of land cover (LC) datasets for the Qiangtang Plateau, High Asia, incorporating 923 field sampling points and seven LC compilations including the International Geosphere Biosphere Programme Data and Information System (IGBPDIS), Global Land cover mapping at 30 m resolution (GlobeLand30), MODIS Land Cover Type product (MCD12Q1), Climate Change Initiative Land Cover (CCI-LC), Global Land Cover 2000 (GLC2000), University of Maryland (UMD), and GlobCover 2009 (Glob-Cover). We initially compared resultant similarities and differences in both area and spatial patterns and analyzed inherent relationships with data sources. We then applied a geographically weighted regression (GWR) approach to predict local accuracy variation. The results of this study reveal that distinct differences, even inverse time series trends, in LC data between CCI-LC and MCD12Q1 were present between 2001 and 2015, with the exception of category areal discordance between the seven datasets. We also show a series of evident discrepancies amongst the LC datasets sampled here in terms of spatial patterns, that is, high spatial congruence is mainly seen in the homogeneous southeastern region of the study area while a low degree of spatial congruence is widely distributed across heterogeneous northwestern and northeastern regions. The overall combined spatial accuracy of the seven LC datasets considered here is less than 70%, and the GlobeLand30 and CCI-LC datasets exhibit higher local accuracy than their counterparts, yielding maximum overall accuracy (OA) values of 77.39% and 61.43%, respectively. Finally, 5.63% of this area is characterized by both high assessment and accuracy (HH) values, mainly located in central and eastern regions of the Qiangtang Plateau, while most low accuracy regions are found in northern, northeastern, and western regions.
防风林带结构是影响防风效能的主要因素。建立不同宽度、不同株行距林带防风效能与林带后距离之间的统计模型，可以为防风林建设提供指导性意见。通过风洞实验，在11 m·s-1风速下，对4种宽度、5种株行距林带的背风面0~10H（H为林带高度）的风速进行测定，采用曲线参数估计法、傅立叶模型、SSF模型（Sum of Sin Functions），构建了不同结构林带防风效能与林带后距离间的统计模型。结果表明：傅立叶模型拟合不同宽度林带的防风效能与林带后距离的关系效果最优，可决系数（R2）均在98%以上；SSF模型拟合不同株行距林带的防风效能与林带后距离的关系效果最优（R2>0.98）。根据构建的统计模型，风速为11 m·s-1左右时，林带宽度8 m（两行一带）的防风林的防风效能存在明显优势；5种株行距的林带中，株行距为8 m×8 m的防风林带本试验条件下防风效果最好。 相似文献
Reinforced concrete (RC) precast shear walls are extensively applied in practical engineering, owing to their fast construction speed. However, because of the transport conditions, RC precast shear walls have to be separated into small wall segments during the factory prefabrication procedure before being assembled on site. Typically, wet-type jointing methods are adopted to link the segments, which is time-consuming and results in unreliable post-pouring area strength. To overcome this problem, the novel scheme of the steel shear key (SSK) featuring steel shear panels and combined fillet and plug welding is proposed. Three RC precast shear wall specimens with different linking strength, termed as weakened SSK wall, standard SSK wall, and strengthened SSK wall, respectively, and an integrated shear wall specimen were designed. Quasi-static cyclic loading was applied to investigate the specimens' dynamic properties. The test results suggest the prefabricated wall segments equipped with SSKs showed reliable stiffness and bearing capacity and were improved in energy dissipation ability, compared with conventional shear walls. As the shear stiffness and number of equipped SSKs increased, the specimens exhibited higher strength, but their ductility and energy dissipation were slightly decreased. Most importantly, the standard SSK wall specimen could achieve satisfactory bearing capacity and deformability and is thus recommended for precast building structures. Finite element method (FEM) models were established to validate the test results, and parametric study analysis was conducted based on the coupling ratio of the SSK walls. Finally, an appropriate coupling ratio range is recommended for practical engineering applications. 相似文献
